(R)-(+)-1,1'-Bi-2-Naphthol

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CAS NO.： 18531-94-7

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Product Detail

Properties

Product name:	R--(+)-1,1'-Bi-2-naphthol
CAS NO. :	18531-94-7
Abbreviation:	(R)-BINOL
Molecular formula:	C₂₀H₁₄O₂
Structural formula:
Related parameters:	Optical rotation (R) :+35 Assay :99% & above Melting point: 208-210 °C (lit.)

Properties

(R)-(+)-1,1'-Bi-2-naphthol has many uses: as an assistant in asymmetric selective reduction of ketones; Ligands in chiral titanium catalysts are used for stereoselective reactions, such as glyoxylic acid reaction and Diels alder reaction; It is used as a chiral promoter in the asymmetric oxidation of sulfide to sulfoxide; Chiral lanthanide trifluoromethanesulfonic acid was synthesized from binaphthol and used as catalyst in asymmetric Diels alder reaction; Binaphthol derivatives have recently been found to be used in asymmetric cleisen rearrangement and asymmetric epoxidation; These lithium aluminum hydride derivatives of binap-h have been widely used in the reduction of ketones; Chiral binaphthol salt precursor, used for olefin epoxidation asymmetric reaction salt.

CAS No.

18531-94-7

Formula

C20H14O2

Molecular Mass

286.32400

Exact Mass

286.09900

PSA

40.46000

Logp

5.07120